Recovery of precious metals from spent automobile catalytic converters using supercritical carbon dioxide

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Muhammad Faisal, Yoichi Atsuta, Hiroyuki Daimon, Koichi Fujie

2008 Asia-Pacific Journal of Chemical Engineering Vol. 3 Issue 4 Article Cited by 38 SDG 12SDG 17 Quartile

Abstract

Recovery of precious metals (platinum, palladium, and rhodium) from a solid matrix sample by supercritical carbon dioxide containing a chelating ligand, a tributyl phosphate (TBP), was studied. The effects of temperature, pressure, and static extraction time on the extraction efficiency were investigated. All experiments were performed using a supercritical fluid extraction system at a temperature range of 40-80°C and a pressure of up to 30 MPa. Results showed that addition of the chelating ligand was necessary to extract the metals. Experiments with pure supercritical carbon dioxide result in no extraction of the metals. It has been observed that the extraction efficiency of metals was strongly dependent on temperature, pressure, and static extraction time. © 2008 Curtin University of Technology and John Wiley & Sons, Ltd.

Affiliations

Department of Chemical Engineering, Syiah Kuala University, Banda Aceh, Indonesia; Department of Ecological Engineering, Toyohashi University of Technology, Toyohashi, Aichi, Tempaku-cho, Japan; International Cooperation Center for Engineering Education Development (ICCEED), Toyohashi University of Technology, Toyohashi, Aichi, Tempaku-cho, Japan; Graduate School of Environment and Information Sciences, Yokohama National University, Hodogaka-ku, Yokohama, 79-7 Tokiwadai, Japan

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