Study of gasification reactivity of some Indonesian coals using thermogravimetry–mass spectrometry (TG-MS) approach

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Agus Haris Widayat, Komang Anggayana, Nurulhuda Halim, Abrar Muslim, Aisyah Al Hamda, Mirza Dian Rifaldi, Mulyono Dwiantoro, Sundek Hariyadi

2026 International Journal of Coal Preparation and Utilization Vol. 46 Issue 5 Article Cited by 0 SDG 7SDG 17 Quartile

Abstract

Four coal samples from the Upper Kutai, South Sumatra, and Meulaboh basins were analyzed using chemical, petrographic, and thermogravimetric–mass spectrometry (TG-MS) methods to characterize their composition and thermal behavior during pyrolysis and gasification. Chemical and petrographic analyses revealed that the samples vary in rank, ranging from sub-bituminous C to high-volatile A bituminous coal (vitrinite reflectance, Rr, between 0.34% and 0.86%). Vitrinite is the predominant maceral, comprising 71.90% to 86.30% by volume. Thermal decomposition during both pyrolysis and gasification was found to be more strongly influenced by coal rank than by maceral composition. During pyrolysis, higher-rank coals exhibited lower thermal decomposition rates. CO₂ was the first gas released during thermal cracking, followed sequentially by CH4, H₂O, and H₂. The latter becoming the dominant gas in the later stages of pyrolysis. In CO₂-driven gasification, the sub-bituminous C coal exhibited a maximum char reactivity of 0.61 mg/min, compared to just 0.01 mg/min for the high-volatile A bituminous coal. Carbon monoxide (CO) was the primary syngas produced during the gasification process. © 2025 Taylor & Francis Group, LLC.

Affiliations

Research Group of Earth Resources Exploration, Mining and Petroleum Engineering Faculty, Institut Teknologi Bandung, Bandung, Indonesia; Research Group of Metallurgical Engineering, Mining and Petroleum Engineering Faculty, Institut Teknologi Bandung, Bandung, Indonesia; Department of Chemical Engineering, Engineering Faculty, Universitas Syiah Kuala, Darussalam, Indonesia; Graduate Program of Mining Engineering, Mining and Petroleum Engineering Faculty, Institut Teknologi Bandung, Bandung, Indonesia; Engineering Faculty, Universitas Kutai Kartanegara, Kalimantan Timur, Tenggarong, Indonesia

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