Effects of organosolv pretreatment and acid hydrolysis on palm empty fruit bunch (PEFB) as bioethanol feedstock

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Nurfahmi, Hwai Chyuan Ong, Badrul Mohamed Jan, Chong Wen Tong, Hadi Fauzi, Wei-Hsin Chen

2016 Biomass and Bioenergy Vol. 95 Article Cited by 47 SDG 17SDG 12 Quartile

Abstract

Biomass synthesis of palm empty fruit bunch (PEFB) into sugars yield as raw material for bioethanol conversion has successfully been performed through organosolv pretreatment and acid hydrolysis processes. These synthesis processes were conducted to evaluate the effect of solvent concentration namely ethanol (C2H5OH) and sulfuric acid (H2SO4), reactions time and temperature against total sugars yield. It is optimized through pretreatment and hydrolysis processes, respectively. The optimum total sugars for pretreatment optimization was obtained 98.89 mg/L which correspond to 55% vol of C2H5OH with reaction time of 60 min at 120 °C. Hydrolysis process for pretreatment optimization was conducted at 1% vol H2SO4, reaction time of 30 min and temperature of 90 °C. The optimum pretreatment conditions were selected for further hydrolysis process with H2SO4 to optimize sugars yield amount in the slurries. The results of acid hydrolysis showed that the optimum amount of total sugars obtained was 133.17 mg/L at concentration H2SO4 0.5% vol with reaction time 30 min and temperature 100 °C. Therefore, it is concluded that organosolv pretreatment and acid hydrolysis can be used as a novel integrated method to optimize the total sugars production synthesized from PEFB to bioethanol. © 2016

Affiliations

Department of Mechanical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur, 50603, Malaysia; Department of Chemical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur, 50603, Malaysia; Department of Chemical Engineering, Faculty of Engineering, Syiah Kuala University, Banda Aceh, 23111, Indonesia; Department of Aeronautics and Astronautics, National Cheng Kung University, Tainan, 701, Taiwan

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