Crystal structure of 4-methoxy-N-(piperidine-1-carbonothioyl)benzamide

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Khairi Suhud, Siti Aishah Hasbullah, Musa Ahmad, Lee Yook Heng, Mohammad B. Kassim

2017 Acta Crystallographica Section E: Crystallographic Communications Vol. 73 Issue 10 Article Cited by 2 SDG 17SDG 9SDG 16 Quartile

Abstract

In the title compound, C14H18N2O2S, the piperidine ring has a chair conformation. Its mean plane is twisted with respect to the 4-methoxybenzoyl ring, with a dihedral angle of 63.0 (3). The central N-C( S)-N(H)-C( O) bridge is twisted with an N-C-N-C torsion angle of 74.8 (6). In the crystal, molecules are linked by N-H...O and C-H...O hydrogen bonds, forming chains along the c-axis direction. Adjacent chains are linked by C-H...φ interactions, forming layers parallel to the ac plane. The layers are linked by offset φ-φ interactions [intercentroid distance = 3.927 (3) Å ], forming a supramolecular three-dimensional structure. © 2017 International Union of Crystallography. All rights reserved.

Affiliations

School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, Selangor, 43600, Malaysia; Department of Chemistry, Mathematic and Natural Science Faculty, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia; Chemical Technology Program, Faculty of Science Technology, Universiti Sains Islam Malaysia, Bandar Baru, Nilai, Nilai, Negeri Sembilan, 71800, Malaysia; Fuel Cell Institute, Universiti Kebangsaan Malaysia, Selangor, 43600, Malaysia

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