Fluorescent carbon quantum dots from Syzygium aromaticum as a selective sensor for Fe3+ and Cd2+ detection in aqueous solution

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Said Ali Akbar, Muhammad Hasan, Muhammad Nazar, Ilham Zulfahmi, Edy Miswar, Muhammad Iqhrammullah, Zulkarnain Jalil

2025 Case Studies in Chemical and Environmental Engineering Vol. 11 Article Cited by 20 SDG 14SDG 6SDG 17 Quartile

Abstract

Fluorescent carbon quantum dots (SA-CQDs) from Syzygium aromaticum were synthesized via carbonization-assisted ultrasonication, exhibiting an average size of 3.314 nm and strong blue fluorescence at 440 nm (excitation: 350 nm) with a quantum yield of 12.61 %. FTIR and UV–vis confirmed oxygen-containing functional groups, enhancing metal ion interactions. SA-CQDs showed selective fluorescence quenching for Fe3+ (89.7 %) and Cd2+ (84.8 %). Sensitivity analysis revealed linearity (R2 = 0.988 for Fe3+, R2 = 0.994 for Cd2+) with detection limits of 0.515 μM and 0.403 μM, respectively. High recovery rates (95.10–100.23 %) in real water samples confirmed reliability for water quality monitoring. © 2025 The Authors

Affiliations

Department of Aquaculture, Faculty of Marine and Fisheries, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia; Department of Chemistry Education, Faculty of Teacher Training and Education, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia; Department of Fisheries Resources Utilization, Faculty of Marine and Fisheries, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia; Postgraduate Program of Public Health, Universitas Muhammadiyah Aceh, Banda Aceh, 23123, Indonesia; Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia

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