Application of picosecond laser-induced breakdown spectroscopy to quantitative analysis of boron in meatballs and other biological samples

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Rinda Hedwig, Kurnia Lahna, Zener Sukra Lie, Marincan Pardede, Koo Hendrik Kurniawan, May On Tjia, Kiichiro Kagawa

2016 Applied Optics Vol. 55 Issue 32 Article Cited by 21 SDG 17SDG 14SDG 12 Quartile

Abstract

This report presents the results of laser-induced breakdown spectroscopy (LIBS) study on biological and food samples of high water content using a picosecond (ps) laser at low output energy of 10 mJ and low-pressure helium ambient gas at 2 kPa. Evidence of excellent emission spectra of various analyte elements with very low background is demonstrated for a variety of samples without the need of sample pretreatment. Specifically, limits of detection in the range of sub-ppm are obtained for hazardous Pb and B impurities in carrots and meatballs. This study also shows the inferior performance of LIBS using a nanosecond laser and atmospheric ambient air for a soft sample of high water content and thereby explains its less successful applications in previous attempts. The present result has instead demonstrated the feasibility and favorable results of employing LIBS with a ps laser and low-pressure helium ambient gas as a less costly and more practical alternative to inductively coupled plasma for regular high sensitive inspection of harmful food preservatives and environmental pollutants. © 2016 Optical Society of America.

Affiliations

Department of Computer Engineering, Bina Nusantara University, 9 K.H. Syahdan, Jakarta, 14810, Indonesia; Department of Physics, Faculty of Mathematics and Natural Sciences, Syiah Kuala University, Darussalam, Banda Aceh, 23111, NAD, Indonesia; Department of Electrical Engineering, University of Pelita Harapan, 1100 M.H. Thamrin Boulevard, Lippo Village, Tangerang, 15811, Indonesia; Research Center of Maju Makmur Mandiri Foundation, 40/80 Srengseng Raya, Jakarta, 11630, Indonesia; Physics of Magnetism and Photonics Group, Faculty of Mathematics and Natural Sciences, Bandung Institute of Technology, 10 Ganesha, Bandung, 40132, Indonesia; Fukui Science Education Academy, Takagi Chuou 2 choume, Fukui, 910-0804, Japan

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