Crystal structure of 4-methoxy-N-[(pyrrolidin-1-yl) carbothioyl]benzamide

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Khairi Suhud, Lee Yook Heng, Siti Aishah Hasbullah, Musa Ahmad, Mohammad B. Kassim, H. Stoeckli-Evans

2015 Acta Crystallographica Section E: Structure Reports Online Vol. 71 Issue 4 Article Cited by 3 SDG 17SDG 12 Quartile

Abstract

In the title compound, C13H16N2O2S, the pyrrolidine ring has a twisted conformation on the central - CH2-CH2- bond. Its mean plane is inclined to the 4-methoxybenzoyl ring by 72.79 (15)°. In the crystal, molecules are linked by N - H⋯O and C - H⋯O hydrogen bonds to the same O-atom acceptor, forming chains along [001]. The chains are linked via slipped parallel π-π interactions [inter-centroid distance = 3.7578 (13) Å], forming undulating slabs parallel to (100).

Affiliations

School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, Selangor, 43600, Malaysia; Department of Chemistry, Mathematics and Natural Science Faculty, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia; Chemical Technology Program, Faculty of Science Technology, Universiti Sains Islam Malaysia, Bandar Baru Nilai, Negeri Sembilan, 71800, Malaysia; Fuel Cell Institute, Universiti Kebangsaan Malaysia, Selangor, 43600, Malaysia; University of Neuchâtel, Switzerland

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